R744 and R290 Refrigerants for Heat Pumps

The Rise of Natural Refrigerants in Commercial Air Source Heat Pumps: R744 and R290 for Schools, Offices and Public Buildings

With legislation tightening and energy costs remaining volatile, now is the time for building managers of schools, offices, local authorities & private sectors to invest in natural refrigerant-based heat pump technologies.
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Beyond F-Gases: The Natural Refrigerant Revolution in Public Building HVAC

As the world moves away from fossil fuels, heating and cooling systems are evolving to meet modern sustainability standards. Among the most exciting solutions are natural refrigerants, particularly R744 (CO₂) and R290 (propane) used in commercial air source heat pumps (ASHPs) for applications such as schools, offices, healthcare buildings, and community centres.

At CO2PEC we design and deliver high efficiency, low carbon heat pump solutions that help the public and private sectors reduce their carbon footprint. In this blog we will investigate why R744 and R290 are becoming the smart refrigerants of choice and how they outperform fossil fuel systems in both effectiveness and environmental impact.


Why Natural Refrigerants?

Refrigerants are crucial to the operation of heat pumps. Synthetic refrigerants like HFCs (Hydrofluorocarbons), are being phased down in the UK and EU due to their high global warming potential (GWP), in line with the F-Gas Regulation. In contrast, natural refrigerants such as R744 and R290 offer an ultra-low GWP, high thermodynamic efficiency and most importantly are non-toxic to the environment.

R744 (CO₂): The Carbon Conscious Choice: R744 is nothing more than carbon dioxide (CO2), a substance found all around us. Unlike many other refrigerants it has a Global Warming Potential (GWP) of 1, the very benchmark against which all other refrigerants are measured. It’s the greenest and cleanest option on the market.


Key Benefits:

  • Ultra-low GWP: As low impact as it gets.
  • Excellent heat transfer properties: R744 systems are highly efficient, especially in colder climates.
  • High-Flow Temperatures (up to 80°): Ideal for retrofitting older buildings often without the need to change the emitters.
  • Non-flammable: R744 is safe to use in public and sensitive environments like schools and hospitals as it the refrigerant is hermetically sealed within our heat pumps.
  • Low Temperature Heating: R744 is equally capable of running low weather compensated flow temperatures for new heating applications.

R744 heat pumps are well suited to large commercial or institutional buildings where continuous high temperature is essential all year round. These systems also offer futureproofing against tightening environmental regulations.


Enter R290, better known as Propane: a truly natural refrigerant. With a remarkably low Global Warming Potential (GWP) of just 3, it’s not just kind to the planet but it also delivers exceptional efficiency particularly in water temperatures below 60°.

Key Benefits:

  • Excellent seasonal efficiency (SCOP): Low energy consumption over time.
  • Lower running temperatures: Ideal for buildings with underfloor heating or modern emitters designed for low temperatures.
  • Non-Toxic and Readily Available: As a natural refrigerant, R290 does not pose the same long-term environmental and health risks as some synthetic refrigerants and can offer cost savings when compared to older HFC refrigerants.

While R290 is flammable, CO2PEC’s commercial ASHPs are engineered with safety in mind with leak detection and strict EU/UK safety compliance making them entirely suitable & highly recommendable for all public & private buildings when correctly designed and installed.


Why R744 and R290 Outperform Fossil Fuels

Heating with fossil fuels like gas and oil typically involves combustion which is not only carbon intensive but also prone to volatility in fuel prices, air quality issues and infrastructure dependence. In contrast:

  • No direct carbon emissions from ASHPs.
  • Energy Efficiencies of around 300–500% (COP 3–5).
  • Future Compliance with F-Gas regulations.
  • Lower Operating costs especially when paired with other green technologies also improving your ROI
  • Improves air quality when not burning fossil fuels.

With heat pumps, energy is moved not generated from combustion, resulting in radically improved energy efficiency. The use of natural refrigerants compounds these benefits offering even cleaner and more sustainable performance.


Supporting Net Zero

For schools, councils, universities and businesses looking to meet Net Zero targets, natural refrigerant heat pumps offer measurable environmental gains:

  • Considerable reductions in CO₂ emissions compared to legacy systems.
  • Integrating with solar PV and battery storage, a system can achieve lower running costs and a faster ROI. This pairing can transform the consumer into an active energy manager.
  • Long equipment lifespan with lower maintenance needs.
  • Contribution to ESG (Environmental, Social & Governance) performance and reporting.

How CO2PEC Can Help

Thinking about upgrading your inefficient and outdated heating & hot water systems? At CO2PEC we provide a full turnkey solution providing high-performance natural refrigerant ASHPs & other renewable solutions across the UK.

From the first feasibility consultation to the final handover, our team manages the entire process. Whether you need to upgrade a school’s heating system or replace fossil fuel boilers in commercial buildings, we deliver end-to-end support, ensuring your transition to a more efficient, sustainable and seamless solution.


Final Thoughts

With legislation tightening and energy costs remaining volatile, now is the time for building managers of schools, offices, local authorities & private sectors to invest in natural refrigerant-based heat pump technologies. R744 and R290 are not only environmentally responsible but they are also the smart economic choice for future proofing your buildings, helping you to avoid the risk of owning high-GWP assets that may soon become obsolete or prohibitively expensive to operate & maintain

Contact CO2PEC today to learn how we can help you transition to a low-carbon, high-efficiency heating solution that stands the test of time.

Visit CO2PEC

Get in touch: enquires@co2pec.com / 01753 905675

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